The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 21, 2026

Filed:

Oct. 07, 2021
Applicant:

Evonik Operations Gmbh, Essen, DE;

Inventors:

Holger Wiederhold, Darmstadt, DE;

David Bolz, Frankfurt, DE;

Jürgen Glenneberg, Offenbach, DE;

Assignee:
Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 29/48 (2006.01); B01D 3/14 (2006.01); B01J 23/42 (2006.01); B01J 31/02 (2006.01); C07C 29/80 (2006.01);
U.S. Cl.
CPC ...
C07C 29/48 (2013.01); B01D 3/143 (2013.01); B01J 23/42 (2013.01); B01J 31/0255 (2013.01); C07C 29/80 (2013.01);
Abstract

A method for preparing 1,2-propanediol involves reacting propene with hydrogen peroxide in the presence of a catalyst mixture, containing a phase transfer catalyst and a heteropolytungstate, in a liquid reaction mixture containing an aqueous phase with a maximum apparent pH of 6 and an organic phase. The method then involves separating the reaction mixture into an aqueous phase (P) containing 1,2-propanediol and formic acid and an organic phase (P); recycling at least part of the separated organic phase (P) to the reaction; contacting at least a part of the separated aqueous phase (P) with a palladium catalyst; and recovering 1,2 propanediol from the aqueous phase provided by the contacting. The contacting of at least a part of the separated aqueous phase (P) with the palladium catalyst reduces the content of formic acid.


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