The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 24, 2026

Filed:

Apr. 24, 2023
Applicants:

National Technology & Engineering Solutions of Sandia, Llc, Albuquerque, NM (US);

Unm Rainforest Innovations, Albuquerque, NM (US);

Inventors:

Christopher Ryan Riley, Albuquerque, NM (US);

Abhaya Datye, Albuquerque, NM (US);

Andrew De La Riva, Albuquerque, NM (US);

Assignees:
Attorneys:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
B01J 23/00 (2006.01); B01J 23/755 (2006.01); C01B 3/40 (2006.01);
U.S. Cl.
CPC ...
B01J 23/005 (2013.01); B01J 23/755 (2013.01); C01B 3/40 (2013.01); C01B 2203/0233 (2013.01); C01B 2203/1058 (2013.01);
Abstract

The present invention is directed to both stoichiometric and sub-stoichiometric high entropy aluminate spinels as a novel high entropy oxide (HEO) crystal phase. Previously reported HEOs are overwhelmingly stoichiometric structures containing a single cationic site and are stabilized solely by intermixing increasing numbers of cations. According to an aspect of the invention, sub-stoichiometric spinels, containing various mixtures of divalent metal cations and cationic vacancies in nominally equimolar concentration, provide entropic stabilization similarly to cations in stoichiometric spinels. The chromatic, structural, and chemical properties of these complex spinels are highly tunable via incorporation of cationic vacancies and multiple divalent metals, enabling their application as unique pigments, catalysts, and thermal coatings.


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