The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 30, 2025

Filed:

Mar. 29, 2021
Applicant:

Dow Global Technologies Llc, Midland, MI (US);

Inventors:

Arkady L. Krasovskiy, Lake Jackson, TX (US);

Ivan A. Konstantinov, Lake Jackson, TX (US);

Hayley A. Brown, Lake Jackson, TX (US);

Mehmet Demirors, Pearland, TX (US);

Assignee:

Dow Global Technologies LLC, Midland, MI (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 2/38 (2006.01); C08F 4/34 (2006.01); C08F 10/02 (2006.01); C08F 293/00 (2006.01);
U.S. Cl.
CPC ...
C08F 293/005 (2013.01); C08F 2/38 (2013.01); C08F 4/34 (2013.01); C08F 10/02 (2013.01); C08F 2438/00 (2013.01);
Abstract

Embodiments are directed to a method of making an olefin-based polymer by free-radical polymerization in a reactor system. The method includes initiating a free-radical polymerization of an olefin-based monomer, propagating growth of the olefin-based polymer during continued free-radical polymerization of the olefin-based monomer, and adding to the reactor system a chain transfer agent that terminates the growth of the olefin-based polymer. The chain transfer agent includes a silane. Examples of suitable silanes are: triethylsilane, diethylmethylsilane, tris(trimethylsilyl)silane, n-butylsilane, dimethylphenylsilane, phenylsilane, chlorodimethylsilane, diisopropylaminosilane, 1,2-bis(dimethylsilyl) benzene, 1,3-bis(dimethylsilyl) benzene, 1,4-bis(dimethylsilyl)benzene, 1,1, 3,3-tetramethyldisiloxane, trimethylsilane, (trimethylsilyl)dimethylsilane, and bis(trimethylsilyl)methylsilane.


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