The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 21, 2025

Filed:

Jun. 18, 2025
Applicant:

King Fahd University of Petroleum and Minerals, Dhahran, SA;

Inventors:

Niladri Maity, Dammam, SA;

Samir Barman, Dammam, SA;

Zainab Al-Mansaf, Al-ahasa, SA;

Nabil Al-Yassir, Al-khobar, SA;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 51/41 (2006.01); B01J 27/185 (2006.01); C07C 7/20 (2006.01); C07C 51/09 (2006.01); C07C 67/055 (2006.01); C07F 15/00 (2006.01);
U.S. Cl.
CPC ...
C07C 51/41 (2013.01); B01J 27/185 (2013.01); C07C 7/20 (2013.01); C07C 51/09 (2013.01); C07C 67/055 (2013.01); C07F 15/0066 (2013.01);
Abstract

A method of acrylate salt production includes reacting ethylene gas in the presence of a metal precursor solution including a base, an additive, a metal precursor, a solvent and a ligand, in an autoclave, to form a metal complex intermediate solution. Further, COreacts with the metal complex intermediate solution to form an ester intermediate solution, which is reacted to form an acrylate salt product mixture. The acrylate salt is extracted thereafter. The COis reacted at a temperature in a range from 100° C. to 200° C., where the metal precursor is tetrakis(triphenylphosphine)palladium(0) and the concentration of tetrakis(triphenylphosphine)palladium(0) in the metal precursor solution is in a range from 0.0005M to 0.003M. The additive is sodium formate and the solvent is selected from the group consisting of N-cyclohexyl-2-pyrrolidone, tetrahydrofuran, and combinations thereof. The turnover number is greater than or equal to 100.


Find Patent Forward Citations

Loading…