The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 02, 2025

Filed:

May. 29, 2019
Applicant:

The University of North Carolina AT Charlotte, Charlotte, NC (US);

Inventors:

Thomas Andrew Schmedake, Charlotte, NC (US);

Michael George Walter, Charlotte, NC (US);

Yong Zhang, Charlotte, NC (US);

Margaret Kocherga, Charlotte, NC (US);

Assignee:
Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
H10K 85/40 (2023.01); C07F 7/02 (2006.01); C09K 11/06 (2006.01); H10K 50/16 (2023.01); H10K 85/60 (2023.01); H10K 101/30 (2023.01);
U.S. Cl.
CPC ...
H10K 85/40 (2023.02); C07F 7/025 (2013.01); C09K 11/06 (2013.01); C09K 2211/1018 (2013.01); H10K 50/16 (2023.02); H10K 85/654 (2023.02); H10K 85/6572 (2023.02); H10K 2101/30 (2023.02);
Abstract

A variety of hexacoordinate pincer complexes are described herein having electronic structure advantageous for electronic and/or optoelectronic applications. In some embodiments, the pincer complexes are luminescent, exhibiting fluorescence and/or phosphorescence. Briefly, a hexacoordinate complex comprises a central atom selected from the group consisting of silicon, germanium, and tin, and two pincer ligands bound to the central atom, wherein the hexacoordinate complex is luminescent. In another aspect, a hexacoordinate complex comprises a central atom selected from the group consisting of silicon, germanium and tin, and two pincer ligands bound to the central atom, wherein the difference between the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) of the hexacoordinate complex is at least 1.5 eV.


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