The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 29, 2025

Filed:

Dec. 29, 2020
Applicant:

Fudan University, Shanghai, CN;

Inventors:

Tao Tu, Shanghai, CN;

Yaliang Shen, Shanghai, CN;

Qingshu Zheng, Shanghai, CN;

Assignee:

FUDAN UNIVERSITY, Shanghai, CN;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 231/10 (2006.01); B01J 31/20 (2006.01); B01J 31/22 (2006.01); C07F 15/00 (2006.01);
U.S. Cl.
CPC ...
C07C 231/10 (2013.01); B01J 31/20 (2013.01); B01J 31/2273 (2013.01); C07F 15/0033 (2013.01); B01J 2231/40 (2013.01); B01J 2531/827 (2013.01);
Abstract

A method for preparing formamide compounds via hydrogenation of carbon dioxide catalyzed by porous materials includes the following steps: by taking porous organometallic polymers as catalysts, reacting amine compounds with carbon dioxide and hydrogen under an air atmosphere to prepare formamide compounds. The method has the advantages of high reaction efficiency, good selectivity, mild conditions, economy, environmental protection, and simple operation. The catalysts are solid organometallic polymers with large specific surface area, strong carbon dioxide adsorption, hierarchical pore distribution, and uniformly dispersed metal centers. They are designed and synthesized as the reaction catalysts by changing the proportion of the cross-linked comonomer. The catalysts can be especially used for catalytic synthesis of fine chemical N, N-dimethylformamide (DMF) without addition of any additional solvent, alkali, or other additives, which is convenient for separation and purification of DMF.


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