The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 15, 2025

Filed:

Feb. 18, 2022
Applicant:

Advanced Energy Materials, Llc, Louisville, KY (US);

Inventors:

Mahendra Sunkara, Louisville, KY (US);

Sivakumar Vasireddy, Louisville, KY (US);

Juan He, Louisville, KY (US);

Assignee:

ADEM Technologies Inc., Louisville, KY (US);

Attorneys:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
B01J 20/28 (2006.01); B01D 19/00 (2006.01); B01J 20/06 (2006.01); B01J 20/08 (2006.01); B01J 20/12 (2006.01); B01J 20/30 (2006.01); B01J 23/755 (2006.01); B01J 23/883 (2006.01); B01J 35/23 (2024.01); B01J 37/08 (2006.01); C10G 25/00 (2006.01); C10G 29/04 (2006.01); C10G 29/16 (2006.01);
U.S. Cl.
CPC ...
B01J 20/28023 (2013.01); B01D 19/0005 (2013.01); B01J 20/06 (2013.01); B01J 20/08 (2013.01); B01J 20/12 (2013.01); B01J 20/28007 (2013.01); B01J 20/3078 (2013.01); B01J 20/3085 (2013.01); B01J 23/755 (2013.01); B01J 23/883 (2013.01); B01J 35/23 (2024.01); B01J 37/08 (2013.01); C10G 25/003 (2013.01); C10G 29/04 (2013.01); C10G 29/16 (2013.01); C10G 2300/202 (2013.01);
Abstract

The present invention is a method for removing sulfur from liquid hydrocarbon feedstocks and for performing hydrogenation reactions in sulfur-contaminated feedstocks, including the hydrogenation of naphthalene in the presence of sulfur compounds, using catalysts or adsorbents comprising metal oxide nanowires decorated with reduced catalytically-active metal particles. In a preferred embodiment, the adsorbent comprises zinc oxide nanowires decorated with catalytically-active metals selected from nickel, cobalt, molybdenum, platinum, palladium, copper, oxides thereof, alloys thereof, and combinations thereof. In some embodiments, the sulfur is removed through a desulfurization process without an external hydrogen supply. The process is effective for the removal of sulfur from diesel fuels and liquid fuel streams, and for deep desulfurization of natural gas streams. The process is also effective for the selective hydrogenation of naphthalene to tetralin in the presence of sulfur compounds.


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