The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 08, 2025

Filed:

Oct. 08, 2021
Applicant:

Ut-battelle, Llc, Oak Ridge, TN (US);

Inventors:

Xi Chen, Oak Ridge, TN (US);

Nancy J. Dudney, Oak Ridge, TN (US);

Sergiy Kalnaus, Oak Ridge, TN (US);

Max J. Palmer, Oak Ridge, TN (US);

Andrew S. Westover, Oak Ridge, TN (US);

Assignee:

UT-BATTELLE, LLC, Oak Ridge, TN (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
H01M 50/403 (2021.01); H01M 10/0525 (2010.01); H01M 10/0565 (2010.01); H01M 50/409 (2021.01); H01M 50/414 (2021.01); H01M 50/434 (2021.01); H01M 50/446 (2021.01);
U.S. Cl.
CPC ...
H01M 50/446 (2021.01); H01M 10/0525 (2013.01); H01M 10/0565 (2013.01); H01M 50/403 (2021.01); H01M 50/409 (2021.01); H01M 50/414 (2021.01); H01M 50/434 (2021.01); H01M 2300/0082 (2013.01); H01M 2300/0085 (2013.01);
Abstract

A method for manufacturing an improved thin film composite solid electrolyte is provided. The method includes spray coating an aqueous suspension of ceramic particles onto a substrate to form a ceramic thin film. The film is sintered to form a porous ceramic structure having an interconnected necked morphology that defines cavities. The cavities are backfilled with an polymer electrolyte, for example a crosslinkable poly(ethylene oxide) (PEO)-based polymer electrolyte. The resulting thin film composite solid electrolyte is highly ionically conductive and mechanically robust with good manufacturability, particularly suitable for, but not limited to lithium metal batteries. The present method represents a departure from conventional mixing-then-casting methods and instead includes the fabrication of a solid electrolyte having a high ceramic volume fraction, high ionic conductivity, low thickness, and good chemical stability with metallic lithium.


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