The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 27, 2025

Filed:

Jan. 20, 2023
Applicant:

King Fahd University of Petroleum and Minerals, Dhahran, SA;

Inventors:

Chanbasha Basheer, Dhahran, SA;

Hakimu Nsubuga, Dhahran, SA;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B32B 9/00 (2006.01); C02F 1/461 (2023.01); C02F 1/467 (2023.01); C23C 18/12 (2006.01); C25B 11/043 (2021.01); C25B 11/057 (2021.01); C25B 11/091 (2021.01); C02F 101/30 (2006.01); C02F 103/00 (2006.01);
U.S. Cl.
CPC ...
C02F 1/46109 (2013.01); C02F 1/4672 (2013.01); C23C 18/1254 (2013.01); C25B 11/043 (2021.01); C25B 11/057 (2021.01); C25B 11/091 (2021.01); C02F 2001/46142 (2013.01); C02F 2001/46147 (2013.01); C02F 2101/30 (2013.01); C02F 2101/308 (2013.01); C02F 2103/003 (2013.01); C02F 2201/4619 (2013.01); C02F 2305/026 (2013.01);
Abstract

Copper-boron-ferrite (Cu—B—Fe) composites may be prepared and immobilized on graphite electrodes in a silica-based sol-gel, e.g., from rice husks. Different bimetallic loading ratios can produce fast in-situ electrogeneration of reactive oxygen species, HOand ·OH, e.g., via droplet flow-assisted heterogeneous electro-Fenton reactor system. Loading ratios of, e.g., 10 to 30 wt. % Feand 5 to 15% wt. Cu, can improve the catalytic activities towards pharmaceutical beta blockers (atenolol and propranolol) degradation in water. Degradation efficiencies of at least 99.9% for both propranolol and atenolol in hospital wastewater were demonstrated. Radicals of ·OH in degradation indicate a surface mechanism at inventive cathodes with correlated contributions of iron and copper. Copper and iron can be embedded in porous graphite electrode surface and catalyze the conversion of HOto ·OH to enhance the degradation. Inventive cathodes can be stable catalytically after 20 or more cycles under neutral and acidic conditions.


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