The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 06, 2025

Filed:

Oct. 27, 2021
Applicant:

The Trustees of Boston College, Chestnut Hill, MA (US);

Inventors:

Jia Niu, Lexington, MA (US);

Hanchu Huang, Newton, MA (US);

Wenqi Wang, Brighton, MA (US);

Assignee:

The Trustees of Boston College, Chesnut Hill, MA (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C08G 61/12 (2005.12);
U.S. Cl.
CPC ...
C08G 61/12 (2012.12); C08G 2261/11 (2012.12); C08G 2261/122 (2012.12); C08G 2261/126 (2012.12); C08G 2261/164 (2012.12); C08G 2261/418 (2012.12);
Abstract

Radical cascade reactions enabling sequence-controlled ring-closing polymerization and ring-opening polymerization for the controlled synthesis of polymers with complex main-chain structures are provided. Facile syntheses leading to low-strain macrocyclic monomers consisting of the ring-opening triggers and extended main-chain structures are also provided. The present disclosure further provides methods for excellent control over polymer molecular weights and molecular weight distributions and high chain-end fidelity allows for the preparation of polymeric systems with well-defined architectures. Further provided are the general nature of the radical cascade-triggered transformations in polymer chemistry, and its application to the synthesis of polymers with diverse main-chain structural motifs with tailored functions. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.


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