The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 25, 2025

Filed:

Jul. 15, 2019
Applicants:

Matthew Becker, Chapel Hill, NC (US);

Yongjun Shin, Fairlawn, OH (US);

Gaelle Le Fer, Akron, OH (US);

Inventors:

Matthew Becker, Chapel Hill, NC (US);

Yongjun Shin, Fairlawn, OH (US);

Gaelle Le Fer, Akron, OH (US);

Assignee:

The University of Akron, Akron, OH (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08G 63/58 (2006.01); B29C 64/314 (2017.01); B33Y 40/10 (2020.01); B33Y 70/00 (2020.01); C08G 63/83 (2006.01); B29K 105/00 (2006.01);
U.S. Cl.
CPC ...
C08G 63/58 (2013.01); B29C 64/314 (2017.08); B33Y 40/10 (2020.01); B33Y 70/00 (2014.12); C08G 63/83 (2013.01); B29K 2105/0002 (2013.01);
Abstract

In various embodiments, the present invention is directed to a PPF-based copolymer for 3D printing applications and methods for its making and use. These copolymers have a viscosity in a printable viscosity range and allow light transmittance at curing wavelengths. In various embodiments, a lower viscosity copolymers are obtained by substitution of a portion of maleic anhydride with succinic anhydride and then forming a poly(propylene fumarate-co-succinate) copolymer by the copolymerization of maleic anhydride and succinic anhydride with propylene oxide via Mg(BHT)(THF)catalyzed ring opening copolymerization (ROCOP). Because of their lower viscosities, these copolymers require less, if any, diethyl fumarate (DEF) to prepare the 3D printing resin, while the mechanical properties can still be adjusted as with a PPF polymer prepared without the succinic anhydride.


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