The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 11, 2025

Filed:

Aug. 14, 2024
Applicant:

Central South University, Changsha, CN;

Inventors:

Chenyang Zhang, Changsha, CN;

Mingjun Han, Changsha, CN;

Wei Sun, Changsha, CN;

Jie Li, Changsha, CN;

Wenjihao Hu, Changsha, CN;

Heng Yu, Changsha, CN;

Rong Wang, Changsha, CN;

Siyuan Liu, Changsha, CN;

Xiangsong Meng, Changsha, CN;

Pan Chen, Changsha, CN;

Assignee:

CENTRAL SOUTH UNIVERSITY, Changsha, CN;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C02F 1/52 (2023.01); C01G 49/12 (2006.01); C02F 1/66 (2023.01); C02F 101/20 (2006.01); C02F 103/34 (2006.01);
U.S. Cl.
CPC ...
C02F 1/5236 (2013.01); C01G 49/12 (2013.01); C02F 1/66 (2013.01); C01P 2004/03 (2013.01); C02F 2101/20 (2013.01); C02F 2103/346 (2013.01);
Abstract

A method for recycling a copper-containing wastewater from a micro-etching is provided, including: modifying a FeS material with a monomer including both carboxyl and sulfhydryl, a crosslinking agent, and a stabilizing and dispersing agent to obtain a FeS-based pH-responsive material CMC-FeS@HS #SiO#COOH, adding the FeS-based pH-responsive material to weakly-acidic copper-containing wastewater from the micro-etching to allow a reaction, and conducting processes such as sulfide precipitation, exchange, adsorption complexation, and flocculation precipitation to finally obtain a precipitate with CuS as a main component. This method makes full use of the pH responsiveness and abundant surface active sites of the FeS-based pH-responsive material, and can control a recovery rate of copper ions in the wastewater at 99.8% or more merely by adjusting a pH value of the copper-containing wastewater from the micro-etching.


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