The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 21, 2025

Filed:

Mar. 17, 2021
Applicant:

Uchicago Argonne, Llc, Chicago, IL (US);

Inventors:

Michael M. Thackeray, Naperville, IL (US);

Eungje Lee, Naperville, IL (US);

Jason R. Croy, Plainfield, IL (US);

Assignee:

UCHICAGO ARGONNE, LLC, Chicago, IL (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
H01M 4/505 (2010.01); H01M 4/131 (2010.01); H01M 4/36 (2006.01); H01M 4/525 (2010.01); H01M 10/0525 (2010.01);
U.S. Cl.
CPC ...
H01M 4/505 (2013.01); H01M 4/131 (2013.01); H01M 4/366 (2013.01); H01M 4/525 (2013.01); H01M 10/0525 (2013.01); Y02E 60/10 (2013.01);
Abstract

Cation-stabilized materials and compositions are described herein, which suppress the structural and electrochemical instability of lithium-metal-oxide spinel and lithiated lithium-metal-oxide spinel electrodes for lithium batteries, notably lithium-ion batteries. The lithium metal oxide electrode material comprises a disordered rock salt structure with partial lithiated-spinel character, wherein, for example, the disordered rock salt structure comprises a formula Li(M″M'″)O, which has the crystallographic formula: [LiM′″][M″M′″Li]Owherein 16c and 16d refer to the octahedral sites of the prototypic space group symmetry Fdm; M″ and M′″ are metal ions; 0<a≤0.5; and 0<b<0.5. These stabilized materials are useful as positive electrodes for lithium batteries in their own right or when used as a structural component to stabilize layered metal oxide electrode systems, such as a two-component layered-layered system or a multi-component layered-layered-spinel system.


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