The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 10, 2024

Filed:

Oct. 28, 2021
Applicant:

Lummus Technology Llc, Bloomfield, NJ (US);

Inventors:

Rosette Barias, Spring, TX (US);

Michael Jon Scott, Houston, TX (US);

Liang Chen, Houston, TX (US);

Assignee:

LUMMUS TECHNOLOGY LLC, Houston, TX (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 5/05 (2006.01); B01D 3/00 (2006.01); B01J 8/02 (2006.01); B01J 8/26 (2006.01); C07C 2/26 (2006.01); C07C 2/28 (2006.01); C07C 5/03 (2006.01); C07C 41/05 (2006.01); C07C 41/06 (2006.01);
U.S. Cl.
CPC ...
C07C 2/26 (2013.01); B01D 3/009 (2013.01); B01J 8/0278 (2013.01); B01J 8/26 (2013.01); C07C 2/28 (2013.01); C07C 5/03 (2013.01); C07C 5/05 (2013.01); C07C 41/05 (2013.01); C07C 41/06 (2013.01); C07C 2531/025 (2013.01);
Abstract

A process for the selective dimerization and etherification of isoolefins. The process including feeding a mixed C5 stream to a selective hydrogenation unit to convert dienes to olefins and isoolefins, producing a hydrogenated effluent stream. The hydrogenated effluent stream is fed to a first fixed bed reactor, producing a first reactor effluent. The first reactor effluent is fed to a catalytic distillation reactor system, producing a first overheads including unreacted olefins, isoolefins, oxygenate, and one or more C5 ethers and a first bottoms including dimers of the isoolefins, any produced trimers of the isoolefins, and heavy oxygenates. The first overheads is fed to a second fixed bed reactor, producing a second reactor effluent including dimers of the isoolefins, unreacted C5s, and unreacted oxygenates. The first bottoms stream and the second reactor effluent are combined and fed to a product splitter, producing a second overheads stream including unreacted C5 olefins, isoolefins, and oxygenates and a second bottoms stream including C10+ hydrocarbons.


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