The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 03, 2024

Filed:

Jul. 30, 2020
Applicant:

Exxonmobil Chemical Patents Inc., Baytown, TX (US);

Inventor:

Xiaoying Bao, Houston, TX (US);

Assignee:
Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 5/48 (2006.01); B01J 23/34 (2006.01); B01J 23/745 (2006.01); B01J 23/75 (2006.01); B01J 23/72 (2006.01); B01J 23/755 (2006.01);
U.S. Cl.
CPC ...
B01J 23/75 (2013.01); B01J 23/34 (2013.01); B01J 23/745 (2013.01); C07C 5/48 (2013.01); C07C 2523/34 (2013.01); C07C 2523/745 (2013.01); C07C 2523/75 (2013.01);
Abstract

Metal oxides are provided that have selective hydrogen combustion activity while also acting as solid oxygen carriers (SOCs). The metal oxides correspond to a metal oxide core of at least one metal having multiple oxidation states that is modified with an alkali metal oxide and/or alkali metal halogen (such as an alkali metal chloride). The resulting modified metal oxide, corresponding to a solid oxygen carrier, can allow for selective combustion of hydrogen while reducing or minimizing combustion of hydrocarbons, such as within a propane dehydrogenation environment. Additionally, it has been unexpectedly found that modifying the core metal oxide with the alkali metal oxide and/or alkali metal chloride can also mitigate coke formation on the solid oxygen carrier. Methods of using such metal oxides for selective hydrogen combustion are also provided.


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