The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 29, 2024

Filed:

Oct. 13, 2021
Applicant:

The Trustees of Columbia University IN the City of New York, New York, NY (US);

Inventors:

Lauren Elizabeth Marbella, New York, NY (US);

Amrita Sarkar, New York, NY (US);

Richard May, New York, NY (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
H01M 10/42 (2006.01); B29B 17/02 (2006.01); C08J 11/28 (2006.01); H01M 4/62 (2006.01);
U.S. Cl.
CPC ...
H01M 10/4242 (2013.01); B29B 17/02 (2013.01); C08J 11/28 (2013.01); H01M 4/623 (2013.01); B29B 2017/0244 (2013.01); B29B 2017/0289 (2013.01); B29B 2017/0293 (2013.01); C08J 2327/16 (2013.01);
Abstract

Materials such as poly(vinylidene fluoride) (PVDF) and lithium cobalt (III) oxide (LCO) are recovered and recycled from cathode films isolated from end-of-life batteries, including lithium-ion batteries. Cathode films are immersed in solution including N,N-dimethylformamide (DMF), N-methyl-2-pyrrolidine (NMP), a tetrahydrofuran (THF):NMP mixture, or a THF:DMF mixture. The solution is able to dissolve PVDF, which can then be separated from LCO and a conductive substrate component of the cathode films via alumina column separation. A PVDF product can be precipitated and recovered, while the LCO and conductive substrate can be recovered directly from the alumina column separator. Both the PVDF and LCO are of suitable quality for use in new cathode films. Such recovery is shown to be achievable even at low solid to liquid ratio during the dissolution process. Thus, economically feasible solvent-based recycling of battery cathodes is enabled to prolong the service life of cathode materials and reduce polymeric waste.


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