Layered sodium ion battery positive electrode material and preparation method therefor

Abstract

A layered sodium ion battery positive electrode material and a preparation method therefor. The chemical formula of the layered sodium ion battery positive electrode material is NaMnO(MO), wherein 0<x≤1, 0.01≤a≤0.2, and M is one or two of W and Mo. The preparation method comprises: preparing a manganese salt solution and a basic potassium permanganate solution mixed with an M element material, wherein the M element material is one or two of molybdate or tungstate; adding the basic potassium permanganate solution to the manganese salt solution, and potassium permanganate solution to the manganese salt solution, and after a reaction is finished, carrying out solid-liquid separation to obtain a solid material; and washing and drying the solid material, mixing the solid material with a sodium source, and then sintering same to obtain a layered sodium ion battery positive electrode material. The layered sodium ion battery positive electrode material of the present invention enhances the framework structure of the material due to the doping of the tungsten or molybdenum element, inhibits the phase change of the material during the charging and discharging process, and can significantly improve the specific capacity, the cycle performance and the rate capability of the material.