The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 10, 2024

Filed:

Feb. 22, 2019
Applicants:

Bp P.l.c., London, GB;

Bp (China) Holdings Ltd, Shanghai, CN;

Inventors:

Benjamin James Dennis-Smither, Hull, GB;

John Glenn Sunley, Hull, GB;

Zhiqiang Yang, Liaoning, CN;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 41/09 (2006.01); B01J 29/06 (2006.01); B01J 29/08 (2006.01); B01J 29/18 (2006.01); B01J 29/40 (2006.01); B01J 29/70 (2006.01);
U.S. Cl.
CPC ...
C07C 41/09 (2013.01); B01J 29/06 (2013.01); B01J 29/084 (2013.01); B01J 29/18 (2013.01); B01J 29/40 (2013.01); B01J 29/7007 (2013.01); B01J 29/7042 (2013.01); B01J 29/7046 (2013.01); B01J 2229/42 (2013.01);
Abstract

A process for dehydrating methanol to dimethyl ether product in the presence of a catalyst and a promoter, wherein the catalyst is at least one aluminosilicate zeolite, wherein: —the aluminosilicate zeolite is selected from: (i) a zeolite having a 2-dimensional framework structure comprising at least one channel having a 10-membered ring, and having a maximum free sphere diameter of at least 4.8 Angstroms; (ii) a zeolite having a 3-dimensional framework structure comprising at least one channel having a 10-membered ring; or (iii) a zeolite comprising at least one channel having a 12-membered ring; —the promoter is selected from one or more compounds of Formula I: (I) wherein Y is selected from a C-Chydrocarbyl substituent, and wherein each of X and any or all of the Z's may independently be selected from hydrogen, halide, a substituted or unsubstituted hydrocarbyl substituent, or a compound of the formula —CHO, —COR, —COR, or —OR, where R is hydrogen or a substituted or unsubstituted hydrocarbyl substituent, and wherein the molar ratio of promoter to methanol is maintained at less than 1.


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