The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 02, 2024

Filed:

Jun. 09, 2021
Applicant:

University of North Texas, Denton, TX (US);

Inventors:

Mohammad A. Omary, Denton, TX (US);

Teresa D. Golden, Denton, TX (US);

Sreekar B. Marpu, Denton, TX (US);

Waleed K. Yaseen, Denton, TX (US);

Assignee:

UNIVERSITY OF NORTH TEXAS, Denton, TX (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
B05D 3/06 (2006.01); B05D 3/14 (2006.01); B05D 7/14 (2006.01); C08F 220/24 (2006.01); C09D 5/08 (2006.01); C09D 133/16 (2006.01); C09D 171/02 (2006.01); C22C 21/00 (2006.01); C23F 1/36 (2006.01);
U.S. Cl.
CPC ...
B05D 3/067 (2013.01); B05D 3/142 (2013.01); B05D 7/14 (2013.01); C08F 220/24 (2013.01); C09D 5/082 (2013.01); C09D 133/16 (2013.01); C09D 171/02 (2013.01); C22C 21/00 (2013.01); C23F 1/36 (2013.01); B05D 2202/25 (2013.01); B05D 2502/00 (2013.01);
Abstract

The hydrophobic and corrosion resistive film of cross-linked poly(hexafluoroisopropyl methacrylate) was prepared by photopolymerization. The starting materials were a monomer of 1,1,1,3,3,3-hexafluoroisopropyl methacrylate, a photoinitiator of hydroxycyclohexyl phenyl ketone, and a cross-linker of poly(ethyleneglycol diacrylate). Photopolymerization was used to start polymerization and to cure the polymer film on an aluminum surface. Drop-casting was used to deposit the fluoropolymer onto an aluminum substrate (AA 3003). The fluoropolymer film has high corrosion protection when measured by potentiodynamic polarization and open circuit potential techniques in an aqueous solution of 3.5% NaCl. Fourier-transform infrared spectroscopy was used to monitor the polymerization process. The dynamic contact angle technique was used to measure the hydrophobicity for the fluorinated polymer coating. Thermal stability of the fluorinated polymer was measured using thermogravimetric analysis. Treatment with strong acid followed by contact angle measurements before and after the treatment confirmed the chemical resistance for the coated aluminum.


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