The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 25, 2024

Filed:

Apr. 20, 2022
Applicant:

Agc Inc., Tokyo, JP;

Inventors:

Takeshi Hirai, Tokyo, JP;

Susumu Saito, Tokyo, JP;

Hiroyuki Watabe, Tokyo, JP;

Assignee:

AGC INC., Tokyo, JP;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
H01M 8/1004 (2016.01); C08F 216/14 (2006.01); C08K 3/04 (2006.01); C08K 3/08 (2006.01); C08K 3/22 (2006.01); H01M 8/1039 (2016.01); H01M 8/1072 (2016.01); H01M 8/10 (2016.01);
U.S. Cl.
CPC ...
C08F 216/1475 (2020.02); C08K 3/04 (2013.01); C08K 3/08 (2013.01); C08K 3/22 (2013.01); H01M 8/1004 (2013.01); H01M 8/1039 (2013.01); H01M 8/1072 (2013.01); C08K 2003/2244 (2013.01); H01M 2008/1095 (2013.01);
Abstract

The present invention provides a fluoropolymer containing fluorosulfonyl groups capable of forming a polymer electrolyte membrane with high conductivity and hot water resistance, a method for its production, a fluoropolymer containing acid-form sulfonic acid groups and a method for its production, a polymer electrolyte membrane, a membrane-electrode assembly and a polymer electrolyte fuel cell. The method for producing a fluoropolymer containing fluorosulfonyl groups of the present invention comprises copolymerizing a monomer m1 (CF═CFCFO-Q-SOF) and TFE in a reactor at a temperature of from 150 to 200° C. in the presence of a radical polymerization initiator, wherein the radical polymerization initiator is continuously or sequentially added into the reactor so that the concentration of the radical polymerization initiator is kept to at most 2.5 mass ppm of the initial feed of the monomer m1 present in the reactor before initiation of the copolymerization during the copolymerization, and the molar ratio of the total feed of the monomer m1 to the total feed of tetrafluoroethylene is from 1.5 to 20.


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