The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 11, 2024

Filed:

Feb. 18, 2022
Applicant:

International Business Machines Corporation, Armonk, NY (US);

Inventors:

Yumi Kim, San Jose, CA (US);

Amaresh Samuthira Pandian, San Jose, CA (US);

Holt Bui, Santa Clara, CA (US);

Jangwoo Kim, San Jose, CA (US);

Young-Hye Na, San Jose, CA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
H01M 4/38 (2006.01); H01M 4/62 (2006.01); H01M 10/0569 (2010.01); H01M 10/058 (2010.01);
U.S. Cl.
CPC ...
H01M 4/382 (2013.01); H01M 4/388 (2013.01); H01M 4/625 (2013.01); H01M 10/0569 (2013.01); H01M 10/058 (2013.01); H01M 2300/0054 (2013.01);
Abstract

A rechargeable metal halide battery fabricated with a liquid nitrogen treated metallic anode demonstrates a stable cycle life with a slow rate of degradation and high discharge capacity in comparison to battery cells with untreated anodes. The anode, which may be an alkali metal and/or an alkaline earth metal, is pretreated with the liquid nitrogen prior to formation in a battery stack. The liquid nitrogen treatment forms a metal nitride on a surface of the anode that (i) increases the surface area of the anode, (ii) acts as a passivation layer that prevents detrimental SEI-forming side reactions that degrade anodes, and (iii) suppresses dendrite growth. Where the anode is lithium, the metal nitride is lithium nitride (LiN).


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