The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 07, 2024

Filed:

Jan. 05, 2022
Applicant:

Zeon Chemicals L.p., Louisville, KY (US);

Inventors:

Soobum Choi, Louisville, KY (US);

Lawrence J. Justice, Louisville, KY (US);

Mahesh Datla, Friendswood, TX (US);

Assignee:

ZEON CHEMICALS L.P., Louisville, KY (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08C 19/02 (2006.01); B01J 23/44 (2006.01); B01J 38/74 (2006.01); B01J 47/02 (2017.01); C08L 15/00 (2006.01);
U.S. Cl.
CPC ...
C08L 15/005 (2013.01); B01J 23/44 (2013.01); B01J 38/74 (2013.01); B01J 47/02 (2013.01); C08C 19/02 (2013.01);
Abstract

The residual hydrogenation catalyst from the hydrogenated nitrile rubber solution is recovered by using two steps such as (1) the catalyst extraction step with an ammonium salt and water (optionally including an oxidation step) to extract catalyst from the HNBR polymer chain to the solvent and then (2) the separation/column recovery step with the column packed with functional ion exchange resins for the separation of ammonia-catalyst complex from hydrogenated nitrile rubber solution and the column recovery for the high catalyst recovery with functional groups of resins. The ammonium salt for the catalyst extraction step is selected from ammonium chloride, ammonium bromide, ammonium iodide, and ammonium acetate. The functional groups in the functional ion exchange resins for packing the column is selected from thiourea, thiouronium, thiol, amine, diamine, triamine, TMT, dithiocarbamate, and carbodithioate.


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