The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 30, 2024

Filed:

Sep. 02, 2022
Applicant:

Rensselaer Polytechnic Institute, Troy, NY (US);

Inventors:

Sangwoo Lee, Cohoes, NY (US);

Chulsung Bae, Cohoes, NY (US);

Carrie Lynn Trant, Troy, NY (US);

Assignee:
Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
B01J 41/14 (2006.01); C08F 212/08 (2006.01); C08F 212/32 (2006.01); C08J 5/22 (2006.01);
U.S. Cl.
CPC ...
B01J 41/14 (2013.01); C08F 212/08 (2013.01); C08F 212/32 (2013.01); C08J 5/2231 (2013.01); C08J 2325/08 (2013.01);
Abstract

An anion exchange membrane is composed of a copolymer of 1,1-diphenylethylene and one or more styrene monomers, such as 4-tert-butylstyrene. The copolymer includes a backbone substituted with a plurality of ionic groups coupled to phenyl groups on the backbone via hydrocarbyl tethers between about 1 and about 7 carbons in length. High-temperature conditions enabled by these copolymers enhance conductivity performance, making them particularly suitable for use in anion exchange membranes in fuel cells, electrolyzers employing hydrogen, ion separations, etc. The properties of the membranes can be tuned via the degree of functionalization of the phenyl groups and selection of the functional groups, such as quaternary ammonium groups. Several processes can be used to incorporate the desired ionic functional groups into the polymers, such as chloromethylation, radical bromination, Friedel-Crafts acylation and alkylation, sulfonation followed by amination, or combinations thereof.


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