The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 16, 2024

Filed:

Jan. 08, 2020
Applicant:

Soochow University, Suzhou, CN;

Inventors:

Lifen Zhang, Suzhou, CN;

Qun Gao, Suzhou, CN;

Zhenping Cheng, Suzhou, CN;

Kai Tu, Suzhou, CN;

Haihui Li, Suzhou, CN;

Lan Yao, Suzhou, CN;

Xiulin Zhu, Suzhou, CN;

Assignee:

SOOCHOW UNIVERSITY, Suzhou, CN;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 2/38 (2006.01); B01J 19/00 (2006.01); B01J 19/12 (2006.01); C08F 2/46 (2006.01); C08F 112/08 (2006.01); C08F 120/14 (2006.01); C08F 120/32 (2006.01); C08F 120/54 (2006.01); C08F 120/56 (2006.01);
U.S. Cl.
CPC ...
C08F 2/38 (2013.01); B01J 19/0013 (2013.01); B01J 19/0053 (2013.01); B01J 19/128 (2013.01); C08F 2/46 (2013.01); C08F 112/08 (2013.01); C08F 120/14 (2013.01); C08F 120/32 (2013.01); C08F 120/56 (2013.01); B01J 2219/00146 (2013.01); B01J 2219/00277 (2013.01); C08F 2438/01 (2013.01); C08F 2438/03 (2013.01);
Abstract

The present invention provides a 'living' radical polymerization method for a vinyl monomer by near-infrared photothermal conversion. The method comprises irradiating a reactor with near-infrared light of 750-850 nm, wherein the reactor has a first chamber and a second chamber that are isolated from each other, the first chamber contains an organic solution of a near-infrared light responsive croconaine dye, and the second chamber is provided with a closed reaction flask containing a reaction solution, the reaction solution comprises a vinyl monomer, two or more of an ATRP initiator, an ATRP ligand, an ATRP catalyst, an RAFT reagent, a thermal initiator, and an additive, and an organic solvent; and the near-infrared light responsive dye converts the near-infrared light into heat energy, by which the reactor is heated to 50-100° C. to polymerize the monomer in the reaction solution, to obtain polymers with controlled molecular weights and molecular weight distributions.


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