The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 19, 2024

Filed:

Apr. 01, 2021
Applicant:

The United States of America, As Represented BY the Secretary of the Navy, Arlington, VA (US);

Inventors:

Benjamin G. Harvey, Ridgecrest, CA (US);

Kyle E. Rosenkoetter, Ridgecrest, CA (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C08F 36/02 (2006.01); C07C 1/20 (2006.01); C08G 61/02 (2006.01);
U.S. Cl.
CPC ...
C08G 61/02 (2013.01); C07C 1/20 (2013.01); C08F 36/02 (2013.01); C08F 2500/07 (2013.01); C08G 2261/13 (2013.01); C08G 2261/3325 (2013.01); C08G 2261/592 (2013.01); C08G 2261/76 (2013.01);
Abstract

A novel family of cycloalkanes compounds having one or more allylidene functionalities which can be used to create cross-linked thermosets and thermoplastics having thermal stability. An example heptacyclo [6.6.0.00000] tetradecane (HCTD) complex with terminal allylidene groups at the 7- and 12-positions (HCTD-7,12-diallylidene) was generated from norbornadiene via an efficient six-step synthesis. Thermal polymerization at temperatures ranging from 160 to 240° C. yielded a robust cross-linked material with thermal stability up to 485° C. in air, a glass transition temperature of 377° C., and a char yield (600° C.) of 56% in air. Applications include heat resistant composites utilized in the aerospace, electronic, automotive and textile industries.


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