The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 13, 2024

Filed:

Aug. 31, 2020
Applicant:

Nederlandse Organisatie Voor Toegepast-natuurwetenschappelijk Onderzoek Tno, S-Gravenhage, NL;

Inventors:

Franciscus Petrus Felix Van Berkel, Le Petten, NL;

Hendricus Adrianus Johannes Van Dijk, Le Petten, NL;

Paul Dean Cobden, Le Petten, NL;

Willem Gerrit Haije, Le Petten, NL;

Jaap Ferdinand Vente, Le Petten, NL;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 41/09 (2006.01); C07C 41/34 (2006.01); C07C 43/04 (2006.01); C07C 41/01 (2006.01); C01B 3/02 (2006.01); B01D 53/26 (2006.01); B01J 8/04 (2006.01); B01J 19/24 (2006.01);
U.S. Cl.
CPC ...
C07C 41/01 (2013.01); B01D 53/261 (2013.01); B01D 53/268 (2013.01); B01J 8/0492 (2013.01); B01J 19/245 (2013.01); C01B 3/02 (2013.01); C07C 41/09 (2013.01); C07C 41/34 (2013.01); B01J 2208/00628 (2013.01); C01B 2203/0283 (2013.01); Y02P 20/00 (2015.11); Y02P 20/10 (2015.11); Y02P 20/582 (2015.11);
Abstract

The invention relates to an improved process and system for the synthesis of dimethyl ether (DME) from a feedstock comprising Hand CO, wherein x=1-2. The process according to the invention comprises (a) subjecting the gaseous mixture comprising synthesis gas originating from step (c) to DME synthesis by contacting it with a catalyst capable of converting synthesis gas to DME to obtain a gaseous mixture comprising DME; (b) subjecting a gaseous mixture comprising the gaseous mixture originating from step (a) to a separation-enhanced reverse water gas shift reaction; and (c) subjecting the gaseous mixture originating from step (b) to DME/synthesis gas separation to obtain DME and a gaseous mixture comprising synthesis gas, which is recycled to step (a). Herein, the feedstock is introduced in step (a) or step (b) and the molar ratio of Hto COin the gaseous mixture which is subjected to step (b) is at least (x+0.8). Also a system for performing the reaction according to the invention is disclosed.


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