The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 06, 2024

Filed:

Mar. 28, 2022
Applicant:

The Research Foundation for the State University of New York, Binghamton, NY (US);

Inventors:

M. Stanley Whittingham, Vestal, NY (US);

Jia Ding, Binghamton, NY (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
H01M 4/38 (2006.01); H01M 10/054 (2010.01); C01G 31/00 (2006.01); H01M 4/62 (2006.01); C08K 3/04 (2006.01); C08K 3/32 (2006.01); H01M 4/58 (2010.01); C09D 127/06 (2006.01); C08F 14/18 (2006.01); C08L 9/08 (2006.01); H01M 4/02 (2006.01);
U.S. Cl.
CPC ...
H01M 4/381 (2013.01); C01G 31/006 (2013.01); C08K 3/04 (2013.01); C08K 3/32 (2013.01); C09D 127/06 (2013.01); H01M 4/5825 (2013.01); H01M 4/622 (2013.01); H01M 4/623 (2013.01); H01M 4/625 (2013.01); H01M 10/054 (2013.01); C01P 2002/72 (2013.01); C08F 14/18 (2013.01); C08K 2003/328 (2013.01); C08L 9/08 (2013.01); H01M 2004/028 (2013.01);
Abstract

An electrode comprising a space group Pna2VOPOlattice, capable of electrochemical insertion and release of alkali metal ions, e.g., sodium ions. The VOPOlattice may be formed by solid phase synthesis of KVOPO, milled with carbon particles to increase conductivity. A method of forming an electrode is provided, comprising milling a mixture of ammonium metavanadate, ammonium phosphate monobasic, and potassium carbonate; heating the milled mixture to a reaction temperature, and holding the reaction temperature until a solid phase synthesis of KVOPOoccurs; milling the KVOPOtogether with conductive particles to form a conductive mixture of fine particles; and adding binder material to form a conductive cathode. A sodium ion battery is provided having a conductive NaVOPOcathode derived by replacement of potassium in KVOPO, a sodium ion donor anode, and a sodium ion transport electrolyte. The VOPO, preferably has a volume greater than 90 Åper VOPO.


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