The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 30, 2024

Filed:

Apr. 02, 2019
Applicants:

Board of Regents, the University of Texas System, Austin, TX (US);

Northeastern University, Boston, MA (US);

Inventors:

Yi Hong, Irving, TX (US);

Guohao Dai, Boston, MA (US);

Cancan Xu, Arlington, TX (US);

Wen-han Lee, Boston, MA (US);

Assignees:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B33Y 10/00 (2015.01); B33Y 70/00 (2020.01); B29C 64/118 (2017.01); C08F 293/00 (2006.01); C12N 5/00 (2006.01); B29K 71/00 (2006.01); B29K 96/04 (2006.01); B29K 105/00 (2006.01);
U.S. Cl.
CPC ...
C08F 293/005 (2013.01); B29C 64/118 (2017.08); B33Y 10/00 (2014.12); B33Y 70/00 (2014.12); C12N 5/0012 (2013.01); B29K 2071/02 (2013.01); B29K 2096/04 (2013.01); B29K 2105/0061 (2013.01); B29K 2105/0085 (2013.01); B29K 2995/006 (2013.01); B29K 2995/0056 (2013.01); C12N 2513/00 (2013.01); C12N 2533/40 (2013.01);
Abstract

Disclosed herein are hydrogel compositions comprising a triblock copolymer having a formula A-B-A, wherein A is a polycaprolactone (PCL) block or a polyvalerolactone (PVL) block and B is a polyethylene glycol (PEG) block. Also disclosed are methods of making a hydrogel comprising providing a photoinitiator and a triblock copolymer having a formula A-B-A, wherein the triblock copolymer comprises one or more ethylenically unsaturated moieties; and photocrosslinking the triblock copolymer, thereby forming a hydrogel. Also disclosed are methods of printing a three-dimensional (3D) article comprising extruding a printing composition from a deposition nozzle moving relative to a substrate, the printing composition comprising a photoinitiator and any herein disclosed triblock copolymer, wherein the triblock copolymer comprises one or more ethylenically unsaturated moieties; depositing one or more layers comprising the printing composition on the substrate; and photocrosslinking the triblock copolymer to form the printed 3D article.


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