The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 30, 2024

Filed:

Apr. 05, 2019
Applicants:

Lawrence Livermore National Security, Llc, Livermore, CA (US);

Virginia Polytechnic Institute and State University, Blacksburg, VA (US);

Inventors:

Marcus A. Worsley, Livermore, CA (US);

Xiaoyu Zheng, Livermore, CA (US);

Patrick G. Campbell, Livermore, CA (US);

Eric Duoss, Livermore, CA (US);

James Oakdale, Livermore, CA (US);

Christopher Spadaccini, Livermore, CA (US);

Ryan Hensleigh, Livermore, CA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 13/00 (2006.01); B29C 64/124 (2017.01); B33Y 10/00 (2015.01); B33Y 70/00 (2020.01); C08K 3/04 (2006.01); C01B 32/194 (2017.01); C01B 32/198 (2017.01); B29C 64/30 (2017.01); B33Y 40/20 (2020.01); C08F 283/06 (2006.01); C08J 9/28 (2006.01); B29K 105/00 (2006.01);
U.S. Cl.
CPC ...
B29C 64/124 (2017.08); B01J 13/0091 (2013.01); B29C 64/30 (2017.08); B33Y 10/00 (2014.12); B33Y 40/20 (2020.01); B33Y 70/00 (2014.12); C01B 32/194 (2017.08); C01B 32/198 (2017.08); C08F 283/065 (2013.01); C08J 9/286 (2013.01); C08K 3/042 (2017.05); B29K 2105/0061 (2013.01); C01B 2204/22 (2013.01); C01B 2204/26 (2013.01); C01B 2204/32 (2013.01); C01P 2002/82 (2013.01); C01P 2004/03 (2013.01); C01P 2006/10 (2013.01); C08J 2205/026 (2013.01); C08J 2333/08 (2013.01);
Abstract

Disclosed here is a method for making a three-dimensional micro-architected aerogel, comprising: (a) curing a reaction mixture comprising a co-sol-gel material (e.g., graphene oxide (GO)) and at least one catalyst to obtain a crosslinked co-sol-gel (e.g., GO hydrogel); (b) providing a photoresin comprising a solvent, a photoinitiator, a crosslinkable polymer precursor, and a dispersion of the crosslinked co-sol-gel (e.g., GO hydrogel); (c) curing the photoresin using projection microstereolithography layer-by-layer to produce a wet gel having a pre-designed three-dimensional structure; (d) drying the wet gel to produce a dry gel; and (e) pyrolyzing the dry gel to produce a three-dimensional micro-architected aerogel (e.g., graphene aerogel). Also disclosed is a photoresin for projection microstereolithography, comprising a solvent, a photoinitiator, a crosslinkable polymer precursor, and a dispersion of a crosslinked co-sol-gel.


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