The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 09, 2024

Filed:

Mar. 22, 2022
Applicant:

Zhejiang University, Hangzhou, CN;

Inventors:

Xufeng Lin, Hangzhou, CN;

Linxi Yao, Hangzhou, CN;

Shirui Chang, Hangzhou, CN;

Lei Wang, Hangzhou, CN;

Assignee:

Zhejiang University, Zhejiang, CN;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 25/22 (2006.01); C07C 17/013 (2006.01);
U.S. Cl.
CPC ...
C07C 25/22 (2013.01); C07C 17/013 (2013.01); C07C 2602/08 (2017.05);
Abstract

Disclosed are 7,7′-dihalo-3,3,3′,3′-tetramethyl-1,1′-spirobiindane and a preparation method thereof. The 7,7′-dihalo-3,3,3′,3′-tetramethyl-1,1′-spirobiindane is a compound represented by formula I, or an enantiomer, a raceme or a diastereomer thereof. The compound of formula I could be prepared by using a racemic or optically active 3,3,3′,3′-tetramethyl-1,1′-spirobiindane-6,6′-diol as a raw material through a series of reactions. The 7,7′-dihalo-3,3,3′,3′-tetramethyl-1,1′-spirobiindane is a key intermediate for preparing 3,3,3′,3′-tetramethyl-1,1′-spirobiindane-based phosphine ligand compounds represented by formula II or III.


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