The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 02, 2024

Filed:

Oct. 31, 2022
Applicant:

Saudi Arabian Oil Company, Dhahran, SA;

Inventors:

Hashim N. Al Khunaizi, Qatif, SA;

Ahmad A. Jazzar, Riyadh, SA;

Shatha A. Alabbad, Dammam, SA;

Donya A. Sewdan, Dammam, SA;

Qasim Saleem, Khobar, SA;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C01B 39/12 (2006.01); B01J 29/40 (2006.01); B01J 37/08 (2006.01); B01J 37/00 (2006.01); C10G 11/05 (2006.01); C01B 39/06 (2006.01); C01B 39/38 (2006.01); B01J 29/86 (2006.01); C01B 39/02 (2006.01); B01J 37/06 (2006.01);
U.S. Cl.
CPC ...
B01J 29/40 (2013.01); B01J 29/86 (2013.01); B01J 37/0045 (2013.01); B01J 37/06 (2013.01); B01J 37/08 (2013.01); C01B 39/02 (2013.01); C01B 39/06 (2013.01); C01B 39/12 (2013.01); C01B 39/38 (2013.01); C10G 11/05 (2013.01); B01J 2229/16 (2013.01); B01J 2229/37 (2013.01); B01J 2229/38 (2013.01); B01J 2229/40 (2013.01); C10G 2400/20 (2013.01);
Abstract

A method of making a boronated zeolite catalyst includes preparing an initial slurry comprising water, a shape selective zeolite, boric acid, and a weak acid selected from the group consisting of oxalic acid, citric acid, and oxalic acid and citric acid, hydrothermally treating the initial slurry at a temperature of from 70° C. to 90° C. to produce a hydrothermally treated slurry comprising dealuminated zeolite particles, adjusting the pH of the hydrothermally treated slurry to an intermediate pH of from 8 to 9 to produce a basic slurry, after adjusting the pH to the intermediate pH, hydrothermally treating the basic slurry at a temperature of from 70° C. to 90° C. to produce a boronated zeolite slurry, removing liquids from the boronated zeolite slurry to produce a boronated zeolite filtrate, and drying and calcining the boronated zeolite filtrate to produce the boronated zeolite catalyst.


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