The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 26, 2023

Filed:

Oct. 14, 2022
Applicant:

Exelus Inc., Fairfield, NJ (US);

Inventors:

Mitrajit Mukherjee, Livingston, NJ (US);

Vamsi M. Vadhri, Edison, NJ (US);

Zawer Wojokh, Little Falls, NJ (US);

Narendra Joshi, Jersey City, NJ (US);

Assignee:

EXELUS, INC., Fairfield, NJ (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 2/62 (2006.01); B01J 29/08 (2006.01); B01J 29/14 (2006.01); B01J 37/30 (2006.01); B01J 37/08 (2006.01); B01J 29/12 (2006.01); B01J 29/00 (2006.01);
U.S. Cl.
CPC ...
C07C 2/62 (2013.01); B01J 29/005 (2013.01); B01J 29/082 (2013.01); B01J 29/085 (2013.01); B01J 29/087 (2013.01); B01J 29/12 (2013.01); B01J 29/123 (2013.01); B01J 29/126 (2013.01); B01J 29/14 (2013.01); B01J 29/143 (2013.01); B01J 29/146 (2013.01); B01J 37/088 (2013.01); B01J 37/30 (2013.01); B01J 2229/183 (2013.01); B01J 2229/37 (2013.01); C07C 2523/10 (2013.01); C07C 2523/42 (2013.01); C07C 2523/44 (2013.01); C07C 2529/89 (2013.01);
Abstract

This invention describes methods of alkylating isobutane which include a catalytic reaction system comprising a crystalline zeolite catalyst and a rare earth-modified molecular sieve adsorbent (RE-MSA). The crystalline zeolite catalyst comprises sodalite cages and supercages, a Si/Al molar ratio of 20 or less, less than 0.5 weight percent alkali metals; and up to 5 wt % of Pt, Pd and or Ni, and acid-site density (including both Lewis and Brønsted acid sites) of at least 100 mole/gm. The RE-modified molecular sieve adsorbent (Re-MSA) comprising sodalite cages and supercages, a Si/Al molar ratio of 20 or less, less than 1 wt % of alkali metals, RE (rare earth elements) in the range of 10 to 30 wt % and transition metals selected from groups 9-11 in the range from 2 wt % to 10 wt; and acid-site density of no more than 30 mole/gm. The invention also includes methods of making RE-MSA.


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