The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 26, 2023

Filed:

Aug. 26, 2022
Applicant:

King Fahd University of Petroleum and Minerals, Dhahran, SA;

Inventors:

Abdul Malik Peedikakkal, Dhahran, SA;

Hasan Ali Al-Mohsin, Dhahran, SA;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 2/58 (2006.01); B01J 31/16 (2006.01); B01J 35/00 (2006.01); B01J 37/03 (2006.01);
U.S. Cl.
CPC ...
B01J 31/1616 (2013.01); B01J 35/004 (2013.01); B01J 37/031 (2013.01); C07C 2/58 (2013.01); B01J 2231/324 (2013.01); B01J 2531/26 (2013.01); B01J 2531/27 (2013.01); B01J 2531/44 (2013.01); C07C 2531/22 (2013.01);
Abstract

Metal-organic frameworks (MOFs) may have Zn(II), Pb(II), and/or Cd(II) as a central metal ion, a 4,4′-bipyridylethylene (bpe) ligand as a first ligand; and fumaric acid (fum) and/or oxalic acid (ox) as a second ligand, wherein the 4,4′-bipyridylethylene ligands are stacked in the MOF, and wherein a distance between two consecutive 4,4′-bipyridylethylene ligands is less than 5 Å. Cycloadditions, particularly photoinduced [2+2] cycloadditions may be catalyzed by such MOFs, and/or the conversion of photoinduced [2+2] cycloadditions in inventive MOFs may be increased by mechanical force, such as by grinding.


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