The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 19, 2023

Filed:

Nov. 12, 2020
Applicant:

Tongji University, Shanghai, CN;

Inventors:

Ying Wang, Shanghai, CN;

Fengting Li, Shanghai, CN;

Tao Feng, Shanghai, CN;

Assignee:

TONGJI UNIVERSITY, Shanghai, CN;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C02F 1/461 (2023.01); C25B 11/069 (2021.01); C02F 1/467 (2023.01); C25B 11/02 (2021.01); C02F 101/16 (2006.01);
U.S. Cl.
CPC ...
C02F 1/46109 (2013.01); C02F 1/4676 (2013.01); C25B 11/02 (2013.01); C25B 11/069 (2021.01); C02F 2001/46142 (2013.01); C02F 2101/163 (2013.01);
Abstract

A copper integrated electrode with a convertible oxidation state, a preparation method and an application method are provided. The preparation process is based on an electrochemically induced self-growth method. Copper foam is used as a precursor, soaked in a graphene oxide solution, dried, calcined at high temperature and annealed, and then treated with an alkali solution to obtain the copper integrated electrode with the convertible oxidation state. The working electrode prepared by the nano-catalytic material of the present invention has good denitrification performance in the environmental field, which can achieve nearly 100% nitrate removal rate, nearly 100% nitrogen selectivity and long-term stability. These properties are due to the prepared working electrode having an oxidizable copper (I, II/0, I), oxygen vacancy (O) and a one-dimensional nanowire structure. The structure can regulate the adsorption and reduction of intermediate products, resulting in nearly 100% nitrate removal rate and nearly 100% nitrogen selectivity.


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