The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 28, 2023

Filed:

Mar. 18, 2020
Applicant:

Exxonmobil Chemical Patents Inc., Baytown, TX (US);

Inventors:

Seth M. Washburn, Houston, TX (US);

Hsu Chiang, Humble, TX (US);

Umar Aslam, Houston, TX (US);

Wenyih F. Lai, Bridgewater, NJ (US);

Doron Levin, Highland Park, NJ (US);

Tan-Jen Chen, Seattle, WA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 2/86 (2006.01); B01J 29/70 (2006.01);
U.S. Cl.
CPC ...
C07C 2/865 (2013.01); B01J 29/70 (2013.01); B01J 29/7088 (2013.01); C07C 2/864 (2013.01); B01D 2255/204 (2013.01); B01D 2255/206 (2013.01); B01D 2255/2061 (2013.01); B01D 2255/2063 (2013.01); B01D 2255/2065 (2013.01); B01J 2523/20 (2013.01); B01J 2523/30 (2013.01); B01J 2523/37 (2013.01); B01J 2523/3706 (2013.01); B01J 2523/3712 (2013.01); C07C 2529/70 (2013.01);
Abstract

This disclosure provides improved processes for converting benzene/toluene via methylation with methanol/dimethyl ether for producing, e.g., p-xylene. In an embodiment, a process utilizes a methylation catalyst system comprising a molecular sieve catalyst and an auxiliary catalyst. The auxiliary catalyst comprises a metal element selected from Group 2, Group 3, the lanthanide series, the actinide series, and mixtures and combinations thereof. The auxiliary catalyst may comprise the oxide of the metal element. Deactivation of the molecular sieve catalyst can be reduced with the inclusion of the auxiliary catalyst in the methylation catalyst system.


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