The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 21, 2023

Filed:

Sep. 29, 2022
Applicant:

Saudi Arabian Oil Company, Dhahran, SA;

Inventors:
Assignee:
Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C10G 11/05 (2006.01); C10G 11/20 (2006.01); B01J 29/46 (2006.01); B01J 29/40 (2006.01); B01J 37/16 (2006.01); B01J 37/08 (2006.01); B01J 37/02 (2006.01);
U.S. Cl.
CPC ...
C10G 11/05 (2013.01); B01J 29/405 (2013.01); B01J 29/46 (2013.01); B01J 37/0201 (2013.01); B01J 37/088 (2013.01); B01J 37/16 (2013.01); C10G 11/20 (2013.01); C10G 2300/202 (2013.01); C10G 2300/205 (2013.01); C10G 2300/301 (2013.01); C10G 2300/308 (2013.01); C10G 2300/70 (2013.01); C10G 2300/807 (2013.01);
Abstract

A process for upgrading crude oil through steam enhanced catalytic cracking includes contacting crude oil with steam and a cracking catalyst at a mass ratio of steam to crude oil of 0.2-1. The cracking catalyst is a hierarchical mesoporous ZSM-5 zeolite impregnated with phosphorous, cerium, lanthanum, and iron. Contacting the crude oil with steam and the cracking catalyst cracks a portion of the crude oil to produce light olefins, light aromatic compounds, or both. The cracking catalyst is prepared by partially disintegrating a starting ZSM-5 zeolite in a first mixture comprising sodium hydroxide and a surfactant and, after the disintegrating, recrystallizing zeolite constituents in the presence of the surfactant to produce a recrystallized ZSM-5 zeolite having a hierarchical pore structure. The recrystallized ZSM-5 zeolite is recovered and calcined to produce the hierarchical mesoporous ZSM-5 zeolite, which is then impregnated with the phosphorous, lanthanum, cerium, and iron.


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