The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 14, 2023

Filed:

Oct. 13, 2022
Applicant:

Chevron Phillips Chemical Company Lp, The Woodlands, TX (US);

Inventors:

Max P. McDaniel, Bartlesville, OK (US);

Carlton E. Ash, Owasso, OK (US);

Kathy S. Clear, Bartlesville, OK (US);

Eric D. Schwerdtfeger, Bartlesville, OK (US);

Carlos A. Cruz, Kingwood, TX (US);

Jeremy M. Praetorius, Bartlesville, OK (US);

Youlu Yu, Bartlesville, OK (US);

Assignee:

Chevron Phillips Chemical Company LP, The Woodlands, TX (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 10/02 (2006.01); B01J 8/08 (2006.01); B01J 19/24 (2006.01); C08K 3/08 (2006.01); C08K 3/36 (2006.01);
U.S. Cl.
CPC ...
C08F 10/02 (2013.01); B01J 8/08 (2013.01); B01J 19/2455 (2013.01); C08K 3/08 (2013.01); C08K 3/36 (2013.01);
Abstract

Supported chromium catalysts containing a solid oxide and 0.1 to 15 wt. % chromium, in which the solid oxide or the supported chromium catalyst has a particle size span from 0.5 to 1.4, less than 3 wt. % has a particle size greater than 100 μm, and less than 10 wt. % has a particle size less than 10 μm, can be contacted with an olefin monomer in a loop slurry reactor to produce an olefin polymer. Representative ethylene-based polymers produced using the chromium catalysts have a HLMI of 4 to 70 g/10 min, a density from 0.93 to 0.96 g/cm, from 150 to 680 ppm solid oxide (such as silica), from 1.5 to 6.8 ppm chromium, and a film gel count of less than 15 catalyst particle gels per ftof 25 micron thick film and/or a gel count of less than or equal to 50 catalyst particles of greater than 100 μm per five grams of the ethylene polymer.


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