The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 24, 2023

Filed:

Jan. 05, 2023
Applicant:

Tongji University, Shanghai, CN;

Inventors:

Fengting Li, Shanghai, CN;

Yifan Gu, Shanghai, CN;

Hengcong Huang, Shanghai, CN;

Ying Wang, Shanghai, CN;

Assignee:

TONGJI UNIVERSITY, Shanghai, CN;

Attorneys:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
B01J 20/22 (2006.01); B01D 53/04 (2006.01); C07C 7/12 (2006.01); B01J 20/30 (2006.01); B01J 20/281 (2006.01); B01J 20/28 (2006.01); C07F 15/04 (2006.01);
U.S. Cl.
CPC ...
B01J 20/226 (2013.01); B01D 53/0423 (2013.01); B01J 20/281 (2013.01); B01J 20/28052 (2013.01); B01J 20/3085 (2013.01); B01J 20/3092 (2013.01); C07C 7/12 (2013.01); C07F 15/045 (2013.01); B01D 2253/204 (2013.01); B01D 2257/7022 (2013.01); B01D 2259/4009 (2013.01); B01J 2220/52 (2013.01);
Abstract

The present invention provides a metal-organic framework material for the adsorptive separation of acetylene/ethylene mixture and preparation method therefor. The metal-organic framework material is named TJE-2 with a chemical formula of [Ni(pyc)(apyz)], wherein, Ni represents nickel as a metal center, pyc represents the organic ligand 1H-pyrazole-4-carboxylic acid, and apyz represents the organic ligand 2-aminopyrazine. The preparation method is as follows: thoroughly dissolving pyc, apyz and Ni(NO)HO, transferring the mixture to a pressure-resistant closed container for heating reaction, followed by solvent exchange and activation to obtain a homogeneous powder material. The ultra-microporous metal-organic framework material prepared by the present invention features a significantly high CHadsorption capacity, good selectivity, and low raw material costs, and therefore can realize CH/CHseparation at lower costs.


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