The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 03, 2023

Filed:

Oct. 19, 2020
Applicant:

Zhejiang University, Zhejiang, CN;

Inventors:

Yong Wang, Hangzhou, CN;

Shanjun Mao, Hangzhou, CN;

Zhe Wang, Hangzhou, CN;

Assignee:

ZHEJIANG UNIVERSITY, Hangzhou, CN;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 21/18 (2006.01); B01J 23/44 (2006.01); B01J 35/00 (2006.01); B01J 35/02 (2006.01); B01J 37/00 (2006.01); B01J 37/03 (2006.01); B01J 3/04 (2006.01); C07C 45/00 (2006.01); C07C 47/02 (2006.01);
U.S. Cl.
CPC ...
B01J 23/44 (2013.01); B01J 21/18 (2013.01); B01J 35/002 (2013.01); B01J 35/023 (2013.01); C07C 45/002 (2013.01); C07C 47/02 (2013.01); C07C 2521/18 (2013.01); C07C 2523/44 (2013.01);
Abstract

Disclosed are a nitrogen-doped hierarchical-porous carbon-loaded nano-Pd catalyst and a preparation method thereof. The preparation method includes preparing nitrogen-doped hierarchical-porous carbon, mixing the nitrogen-doped hierarchical-porous carbon with water, adjusting a pH value of the mixed solution to be alkaline, mixing the mixed solution with a Pd metal precursor aqueous solution, and then adding a reducing agent to obtain the nitrogen-doped hierarchical-porous carbon-loaded nano-Pd catalyst after reduction. The prepared nitrogen-doped hierarchical-porous carbon-loaded nano-Pd catalyst includes a nitrogen-doped porous carbon material carrier with hierarchical pores and Pd metal nanoparticles loaded in the hierarchical pores of the carrier. The Pd metal nanoparticles have a size of 2˜14 nm and a regular polyhedron shape. The nitrogen-doped hierarchical-porous carbon-loaded nano-Pd catalyst has excellent catalytic performance, especially has ultra-high conversion rate, selectivity and cycle stability in the selective hydrogenation reaction of unsaturated ketones, and is a key to open a new synthetic route of vitamin E.


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