The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 01, 2023

Filed:

Jun. 03, 2020
Applicant:

Board of Regents, the University of Texas System, Austin, TX (US);

Inventors:

Purnendu K. Dasgupta, Arlington, TX (US);

Charles Philip Shelor, Arlington, TX (US);

Hongzhu Liao, Arlington, TX (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
G01N 30/96 (2006.01); G01N 27/44 (2006.01); B01D 15/24 (2006.01); B01D 15/36 (2006.01); G01N 27/447 (2006.01);
U.S. Cl.
CPC ...
G01N 30/96 (2013.01); B01D 15/24 (2013.01); B01D 15/363 (2013.01); G01N 27/44756 (2013.01); B01D 15/367 (2013.01); G01N 2030/965 (2013.01);
Abstract

A permeative amine/acid introduction device (PAID) is placed after a conventional KOH eluent suppressed conductometric anion chromatography (SCAC) system. The PAID converts the suppressed eluites from the acid form to the corresponding salt. For example, when the analytes are acids, they are converted to the corresponding ammonium salt (NRH+HX→NRH+X) and allows very weak acids HX (pK≥7.0) that cannot normally be detected by SCAC to be measured by a second conductivity detector following the PAID. Permeative reagent introduction is dilutionless, can be operated without pumps and provides good mixing with low band dispersion (as small as 30 μL). An exemplary amine is diethylamine (DEA), which was chosen as the amine source due to its low pKvalue (pK3.0), high vapor pressure, and low toxicity and low odor.


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