The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 18, 2023

Filed:

Feb. 26, 2019
Applicant:

King Fahd University of Petroleum and Minerals, Dhahran, SA;

Inventors:

Muhammad Ali Ehsan, Dhahran, SA;

Md. Abdul Aziz, Dhahran, SA;

Abbas Saeed Hakeem, Dhahran, SA;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C23C 16/40 (2006.01); C25B 11/091 (2021.01); C25B 1/04 (2021.01); B01J 23/75 (2006.01); B01J 37/02 (2006.01); B01J 35/00 (2006.01); C25B 11/051 (2021.01); C25B 11/057 (2021.01); C23C 16/448 (2006.01);
U.S. Cl.
CPC ...
C25B 11/091 (2021.01); B01J 23/75 (2013.01); B01J 35/0033 (2013.01); B01J 37/0244 (2013.01); C25B 1/04 (2013.01); C25B 11/051 (2021.01); C25B 11/057 (2021.01); C23C 16/405 (2013.01); C23C 16/4486 (2013.01);
Abstract

A synthetic methodology for robust, nanostructured films of cobalt oxide over metal evaporated gold or similar material layer of, e.g., 50 nm, directly onto glass or other substrates via aerosol assisted chemical vapor deposition (AACVD). This approach allows film growth rates in the range of, e.g., 0.8 nm/s, using a commercially available precursor, which is ˜10-fold the rate of electrochemical synthetic routes. Thus, 250 nm thick cobalt oxide films may be generated in only 5 minutes of deposition time. The water oxidation reaction for such films may start at ˜0.6 V vs Ag/AgCl with current density of 10 mA/cmand is achieved at ˜0.75 V corresponding to an overpotential of 484 mV. This current density is further increased to 60 mA/cmat ˜1.5 V (vs Ag/AgCl). Electrochemically active surface area (ECSA) calculations indicate that the synergy between a Au-film, acting as electron sink, and the cobalt oxide film(s), acting as catalytic layer(s), are more pronounced than the surface area effects.


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