The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.
The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.
Patent No.:
Date of Patent:
Jul. 04, 2023
Filed:
Oct. 06, 2017
3m Innovative Properties Company, St. Paul, MN (US);
Christopher B. Walker, Jr., St. Paul, MN (US);
Matthew R. C. Atkinson, Grant, MN (US);
Mary M. Caruso Dailey, Maplewood, MN (US);
John C. Clark, Maplewood, MN (US);
Vivek Krishnan, St. Paul, MN (US);
Alexander J. Kugel, Woodbury, MN (US);
Steven J. McMan, Stillwater, MN (US);
Abdullahi A. Mohamud, Minnetonka, MN (US);
3M innovative Properties Company, St. Paul, MN (US);
Abstract
Described herein is an article comprising (i) bead film comprising a binder resin layer and a plurality of microspheres partially embedded in the binder resin layer such that a portion of the microspheres outwardly protrude a first distance from the surface of the binder resin layer; (ii) a stabilizing layer disposed on the outwardly protruding microspheres opposite the binder resin layer, wherein the stabilizing layer intimately conforms to the protruding microspheres, and wherein the stabilizing layer has a Tg less than 100 C and a storage modulus at 150° C. of at least 1.5 MPa; and (iii) a release agent, wherein (a) the binder resin layer comprises the release agent, (b) the stabilizing layer comprises the release agent, and/or (c) an intermediate layer comprises the release agent, wherein the intermediate layer is disposed between the monolayer of microspheres and the stabilizing layer, with the proviso that when the binder resin layer has a fluorine content along the polymeric backbone greater than 65 wt %, the stabilizing layer comprises a release agent selected from a silicone and a fluoropolymer. Also disclosed herein are methods of making thermoformable bead films.