The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 16, 2023

Filed:

Jun. 07, 2019
Applicant:

Dow Global Technologies Llc, Midland, MI (US);

Inventors:

Nitin Borse, Pearland, TX (US);

Zhenshuo Bobby Liu, Missouri City, TX (US);

Ian M. Munro, Lake Jackson, TX (US);

Swapnil B. Chandak, Pearland, TX (US);

Assignee:

Dow Global Technologies LLC, Midland, MI (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 4/659 (2006.01); C08F 10/02 (2006.01); C08F 2/44 (2006.01); C08F 2/06 (2006.01); C08F 4/02 (2006.01); C08F 4/655 (2006.01); C08F 210/16 (2006.01);
U.S. Cl.
CPC ...
C08F 2/44 (2013.01); C08F 2/06 (2013.01); C08F 4/025 (2013.01); C08F 4/6555 (2013.01); C08F 210/16 (2013.01); C08F 4/659 (2013.01); C08F 10/02 (2013.01); C08F 2410/01 (2013.01);
Abstract

An activator-nucleator formulation comprising an activating effective amount of (A) an alkylaluminum(chloride) compound (compound (A)); and a nucleating effective amount of a compound (B) selected from at least one of compounds (B1) to (B3): (B1) calcium (1R,2S)-cis-cyclohexane-1,2-dicarboxylate (1:1); (B2) calcium stearate (1:2), and (B3) zinc stearate (1:2); wherein the compound (A) is effective for activating a Ziegler-Natta procatalyst to give a Ziegler-Natta catalyst; and wherein the compound (B) is effective for lowering isothermal crystallization peak time period of a semicrystalline polyethylene polymer made in a polymerization process by the Ziegler-Natta catalyst. A method of polymerizing ethylene, and optionally 0, 1, or more alpha-olefin comonomers, in a polymerization process conducted in a polymerization reactor, the method comprising contacting ethylene, and optionally 0, 1, or more alpha-olefin comonomers, with the Ziegler-Natta catalyst system to give a semicrystalline polyethylene polymer. The semicrystalline polyethylene polymer made by the method of polymerizing.


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