The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 18, 2023

Filed:

Jan. 04, 2019
Applicant:

King Fahd University of Petroleum and Minerals, Dhahran, SA;

Inventors:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08J 3/075 (2006.01); B01J 13/00 (2006.01); C03C 17/30 (2006.01); C03C 17/32 (2006.01); C09D 183/08 (2006.01); C03C 17/00 (2006.01);
U.S. Cl.
CPC ...
C08J 3/075 (2013.01); B01J 13/0021 (2013.01); B01J 13/0039 (2013.01); C03C 17/004 (2013.01); C03C 17/30 (2013.01); C03C 17/32 (2013.01); C09D 183/08 (2013.01); C08J 2483/08 (2013.01);
Abstract

Urea and amine comprising sol-gel hybrid coatings have been developed for numerous applications, including capillary microextraction-high performance liquid chromatographic analysis from aqueous samples. A fused silica capillary may be coated from the inside with surface bonded coating material and may be created by in-situ sol-gel reaction(s). Urea-functionalized coatings can be immobilized on the inner surface of a capillary by condensing silanol groups of capillary and sol-solution. Urea functionalized, sol-gel coated capillaries may be installed, e.g., in HPLC manual injection ports, and optionally pre-concentrated analytes including phenols, ketones, aldehydes, and/or polyaromatic hydrocarbons, from highly polar to non-polar, maybe analyzed by online extraction and high-performance liquid chromatographic. Such coatings may achieve sensitivities with lower detection limits (S/N=3) of 0.10 ng/mL to 14.29 ng/mL, with reproducibilities of <12.0% RSD (n=3), or <10.0% RSD (n=3) by exchanging the capillary of the same size.


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