The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 18, 2023

Filed:

Jul. 31, 2018
Applicants:

Ecole Normale Superieure DE Lyon, Lyons, FR;

Universite Claude Bernard Lyon 1, Villeurbanne, FR;

Centre National DE LA Recherche Scientifique, Paris, FR;

Inventors:

Patrice Baldeck, Vizille, FR;

Akos Banyasz, Lyons, FR;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B29C 35/04 (2006.01); C08F 2/46 (2006.01); C08F 2/50 (2006.01); C08G 61/04 (2006.01); B33Y 10/00 (2015.01); B33Y 40/00 (2020.01); B33Y 70/00 (2020.01); B29C 64/129 (2017.01); B29C 64/371 (2017.01); C09D 11/101 (2014.01); C09D 11/107 (2014.01); G03F 7/00 (2006.01); B29C 64/124 (2017.01); C08J 3/28 (2006.01); G03F 7/20 (2006.01); C08F 222/10 (2006.01);
U.S. Cl.
CPC ...
C08F 2/50 (2013.01); B29C 64/124 (2017.08); B29C 64/129 (2017.08); B29C 64/371 (2017.08); B33Y 10/00 (2014.12); B33Y 40/00 (2014.12); B33Y 70/00 (2014.12); C08J 3/28 (2013.01); C09D 11/101 (2013.01); C09D 11/107 (2013.01); G03F 7/0037 (2013.01); G03F 7/2055 (2013.01); G03F 7/70416 (2013.01); C08F 222/102 (2020.02); C08F 222/103 (2020.02);
Abstract

A photopolymerizable composition comprises at least a polymerizable resin, a photosensitizer, an annihilator, and a photoinitiator. The photosensitizer is formulated to absorb an excitation light signal received in a first range of wavelengths. The annihilator is formulated to emit a light signal in a second range of wavelengths different from the first. During the absorption of light by the photosensitizer in the first range of wavelengths, the annihilator emits a light signal in the second range, a photon energy of the emitted light signal being greater than a photon energy of the light signal received by the photosensitizer. The annihilator is also formulated to implement an energy transfer mechanism to excite the photoinitiator for polymerization of the resin. The excited photoinitiator is formulated to generate at least one polymerizable initiator to cause the polymerization reaction. Related methods, such as three-dimensional printing methods, and materials are also disclosed.


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