The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 28, 2023

Filed:

Apr. 07, 2022
Applicant:

Lyondell Chemical Technology, L.p., Houston, TX (US);

Inventors:

Daniel F. White, Houston, TX (US);

Beaven S. Mandimutsira, Sugar Land, TX (US);

Robert J. Rebman, Pearland, TX (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 45/50 (2006.01); C07C 29/141 (2006.01); B01J 23/755 (2006.01); B01J 31/24 (2006.01);
U.S. Cl.
CPC ...
C07C 45/505 (2013.01); B01J 23/755 (2013.01); B01J 31/2409 (2013.01); B01J 2231/321 (2013.01); B01J 2531/822 (2013.01);
Abstract

A process for the production of 4-hydroxybutyraldehyde is described. The process comprises reacting allyl alcohol with a mixture of carbon monoxide and hydrogen in the presence of methylcyclohexane as a reaction solvent and a catalyst system comprising a rhodium complex and a substituted or unsubstituted diphosphine ligand. The use of the methylcyclohexane increases the reaction rate while also giving a high yield of 4-hydroxybutyraldehyde compared to 3-hydroxy-2-methylpropionaldehyde and improving the separation of the hydroxyaldehyde products from the catalyst system.


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