The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 07, 2023

Filed:

Oct. 19, 2020
Applicant:

Archer-daniels-midland Company, Decatur, IL (US);

Inventors:

Vincent J. Murphy, Stockholm, SE;

James Shoemaker, Gilroy, CA (US);

Guang Zhu, Union City, CA (US);

Raymond Archer, San Jose, CA (US);

George Frederick Salem, Los Altos, CA (US);

Eric L. Dias, Belmont, CA (US);

Assignee:

Archer-Daniels-Midland Company, Decatur, IL (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 51/235 (2006.01); B01J 23/52 (2006.01); B01J 23/42 (2006.01); C07C 51/377 (2006.01); C07C 51/41 (2006.01); C07C 209/00 (2006.01); C07C 253/00 (2006.01); C07D 201/08 (2006.01); C07D 223/10 (2006.01); C07D 309/30 (2006.01); C08G 63/16 (2006.01); C08G 69/14 (2006.01); C08G 69/26 (2006.01); C08G 69/36 (2006.01); B01J 21/06 (2006.01); B01J 21/08 (2006.01); B01J 29/06 (2006.01); B01J 35/00 (2006.01); B01J 37/02 (2006.01); B01J 37/18 (2006.01);
U.S. Cl.
CPC ...
B01J 23/52 (2013.01); B01J 21/063 (2013.01); B01J 21/066 (2013.01); B01J 21/08 (2013.01); B01J 23/42 (2013.01); B01J 29/06 (2013.01); B01J 35/0006 (2013.01); B01J 35/0013 (2013.01); B01J 37/0211 (2013.01); B01J 37/0236 (2013.01); B01J 37/0248 (2013.01); B01J 37/18 (2013.01); C07C 51/235 (2013.01); C07C 51/377 (2013.01); C07C 51/412 (2013.01); C07C 209/00 (2013.01); C07C 253/00 (2013.01); C07D 201/08 (2013.01); C07D 223/10 (2013.01); C07D 309/30 (2013.01); C08G 63/16 (2013.01); C08G 69/14 (2013.01); C08G 69/26 (2013.01); C08G 69/36 (2013.01); C07B 2200/07 (2013.01); Y02P 20/582 (2015.11);
Abstract

Disclosed are catalysts comprised of platinum and gold. The catalysts are generally useful for the selective oxidation of compositions comprised of a primary alcohol group and at least one secondary alcohol group wherein at least the primary alcohol group is converted to a carboxyl group. More particularly, the catalysts are supported catalysts including particles comprising gold and particles comprising platinum, wherein the molar ratio of platinum to gold is in the range of about 100:1 to about 1:4, the platinum is essentially present as Pt(0) and the platinum-containing particles are of a size in the range of about 2 to about 50 nm. Also disclosed are methods for the oxidative chemocatalytic conversion of carbohydrates to carboxylic acids or derivatives thereof. Additionally, methods are disclosed for the selective oxidation of glucose to glucaric acid or derivatives thereof using catalysts comprising platinum and gold. Further, methods are disclosed for the production of such catalysts.


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