The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 28, 2023

Filed:

Apr. 08, 2022
Applicant:

Arizona Board of Regents on Behalf of Arizona State University, Scottsdale, AZ (US);

Inventors:

Daniel Buttry, Tempe, AZ (US);

Joseph Rheinhardt, Phoenix, AZ (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
H01M 10/0568 (2010.01); H01M 10/0565 (2010.01); H01M 10/0569 (2010.01); H01M 10/44 (2006.01);
U.S. Cl.
CPC ...
H01M 10/0568 (2013.01); H01M 10/0565 (2013.01); H01M 10/0569 (2013.01); H01M 10/44 (2013.01); H01M 2300/0025 (2013.01); H01M 2300/0085 (2013.01);
Abstract

Disclosed is a calcium salt, Ca(HMDS), where HMDS is the hexamethyldisilazide anion (also known as bis(trimethylsilyl)amide), enables high current densities and high coulombic efficiency for calcium metal deposition and dissolution. These properties facilitate the use of this salt in batteries based on calcium metal. In addition, the salt is significant for batteries based on metal anodes, which have higher specific energies than batteries based on intercalation anodes, such as LiC. In particular, a calcium based rechargeable battery includes Ca(HMDS)salt and at least one solvent, the solvent suitable for calcium battery cycling. The at least one solvent can be diethyl ether, diisopropylether, methyl t-butyl ether (MTBE), 1,3-dioxane, 1,4-dioxane, tetrahydrofuran (THF), tetrahydropyran, glyme, diglyme, triglyme or tetraglyme, or any mixture thereof.


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