The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 28, 2023

Filed:

Apr. 19, 2022
Applicants:

Board of Regents, the University of Texas System, Austin, TX (US);

Adaptive 3d Technologies, Dallas, TX (US);

Inventors:

Gregory T. Ellson, Dallas, TX (US);

Benjamin R. Lund, Wylie, TX (US);

Walter Voit, Dallas, TX (US);

Assignees:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B29C 64/124 (2017.01); C09D 11/101 (2014.01); C09D 11/102 (2014.01); C09D 11/033 (2014.01); C08G 18/38 (2006.01); C08G 18/08 (2006.01); B33Y 10/00 (2015.01); B33Y 70/00 (2020.01); C08G 18/73 (2006.01); C08G 18/76 (2006.01); C08G 18/72 (2006.01); C08G 18/75 (2006.01); C08G 18/79 (2006.01); C08G 18/20 (2006.01); B29K 75/00 (2006.01);
U.S. Cl.
CPC ...
C09D 11/101 (2013.01); B29C 64/124 (2017.08); B33Y 10/00 (2014.12); B33Y 70/00 (2014.12); C08G 18/089 (2013.01); C08G 18/2063 (2013.01); C08G 18/3876 (2013.01); C08G 18/725 (2013.01); C08G 18/73 (2013.01); C08G 18/752 (2013.01); C08G 18/755 (2013.01); C08G 18/758 (2013.01); C08G 18/7614 (2013.01); C08G 18/7621 (2013.01); C08G 18/7642 (2013.01); C08G 18/7671 (2013.01); C08G 18/792 (2013.01); C09D 11/033 (2013.01); C09D 11/102 (2013.01); B29K 2075/00 (2013.01);
Abstract

A method of three-dimensional stereolithography printing a thiourethane polymer part using the vat resin. Adding a resin to a vat of a three-dimensional stereolithography printer, the resin a liquid mixture including: a first type of monomer including two or more thiol functional groups, a second type of monomer including two or more isocyanate functional groups, a photolatent base, an anionic step-growth polymerization reaction inhibitor and a light absorber. The photolatent base is decomposable upon exposure to a light to form a non-nucleophillic base catalyst having a pKa greater than 7. The anionic step-growth polymerization reaction inhibitor has an acidic group configured to form an acid-base pair with the non-nucleophillic base. The light absorber has an absorbance in the liquid mixture that is greater than an absorbance of the photolatent base at a wavelength of the light used for the exposure.


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