The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 14, 2023

Filed:

Dec. 27, 2021
Applicant:

Umicore Ag & Co. KG, Hanau-Wolfgang, DE;

Inventors:

Herbert Plenio, Bensheim, DE;

Pavlo Kos, Griesheim, DE;

Roman Savka, Griesheim, DE;

Assignee:

Umicore AG & Co. KG, Hanau-Wolfgang, DE;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 31/00 (2006.01); B01J 31/22 (2006.01); C07F 15/00 (2006.01); C07C 217/90 (2006.01); C07C 43/29 (2006.01); C07C 5/31 (2006.01); C07C 43/275 (2006.01);
U.S. Cl.
CPC ...
B01J 31/2208 (2013.01); B01J 31/2273 (2013.01); B01J 31/2278 (2013.01); C07C 5/31 (2013.01); C07C 43/275 (2013.01); C07C 43/29 (2013.01); C07C 217/90 (2013.01); C07F 15/0046 (2013.01); B01J 2231/324 (2013.01); B01J 2231/543 (2013.01); B01J 2531/821 (2013.01); C07C 2531/22 (2013.01);
Abstract

The invention is directed to ruthenium-based metathesis catalysts of the Grubbs-Hoveyda type. The new 2-aryloxy-substituted ruthenium catalysts described herein reveal rapid initiation behavior. Further, the corresponding styrene-based precursor compounds are disclosed. The catalysts are prepared in a cross-metathesis reaction starting from styrene-based precursors which can be prepared in a cost-effective manner. The new Grubbs-Hoveyda type catalysts are suitable to catalyze ring-closing metathesis (RCM), cross metathesis (CM) and ring-opening metathesis polymerization (ROMP). Low catalyst loadings are necessary to convert a wide range of substrates including more complex and critical substrates via metathesis reactions at low to moderate temperatures in high yields within short reaction times.


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